Search results for "porous structure"

Visible light photocatalytic activity of macro-mesoporous TiO2-CeO2inverse opals

2018

Macro-mesoporous TiO2 inverse opal materials were synthesized and they were tested as photocatalysts under visible light irradiation. The influence of cerium oxide addition towards the Rhodamine B (RhB) photodegradation activity was evaluated. Structural, textural, spectral and surface properties of the TiO2-CeO2 inverse opal nanocomposites were studied by XRD, XPS, SEM, TEM, N2 adsorption-desorption, Diffuse Reflectance UV–vis and Photoluminescence spectroscopies. Compared to commercial TiO2 anatase, the macro-mesoporous TiO2 inverse opal exhibited six times higher kinetic rate constant in the RhB degradation under visible light irradiation. The good photocatalytic activity was related to …

PREPARATION AND CHARACTERIZATION OF BIOPOLYMERIC POROUS STRUCTURES FOR ADVANCED APPLICATIONS

Porous biopolymers received an increasing academic and industrial interest finding application in several fields such as tissue engineering, bioprocess intensification and waste removal. Tissue engineering combines the knowledge of materials science and bioengineering in order to develop structures able to substitute and restore the normal function of injured or diseased tissues. In this context, polymeric 3D or 2D scaffolds are widely investigated as temporary cell guidance during the tissue restore. Porous biomaterials can offer a versatile and cost effective way for immobilization of filamentous microorganisms in submerged fermentation processes for the production of biologically active …

Designed biodegradable hydrogel structures prepared by stereolithography using poly(ethylene glycol)/poly(D,L-lactide)-based resins

2010

Designed three-dimensional biodegradable poly(ethylene glycol)/poly(D,L-lactide) hydrogel structures were prepared for the first time by stereolithography at high resolutions. A photo-polymerisable aqueous resin comprising PDLLA-PEG-PDLLA-based macromer, visible light photo-initiator, dye and inhibitor in DMSO/water was used to build the structures. Porous and non-porous hydrogels with well-defined architectures and good mechanical properties were prepared. Porous hydrogel structures with a gyroid pore network architecture showed narrow pore size distributions, excellent pore interconnectivity and good mechanical properties. The structures showed good cell seeding characteristics, and human…

Photocatalytic H2 production over inverse opal TiO2 catalysts

2019

Abstract The influence of BiVO4 and CuO on the chemico-physical properties of TiO2-based systems is reported. The performances of these systems were investigated in the photocatalytic H2 production both under UV and solar light irradiation. The characterization data pointed out that the obtained TiO2 samples have highly porous inverse opal structures with interconnected macropores. Inverse opal TiO2 exhibited higher activity in the H2 production than the commercial TiO2 due to the peculiar porosity that allows photons to enter inside the photocatalyst. A further improvement in terms of photoactivity was verified by addition of increasing amounts of BiVO4. On the contrary a small CuO content…

Wood and Black Liquor-Based N-Doped Activated Carbon for Energy Application

2021

The research was funded by the Latvian Council of Science project “Nanostructured Nitrogenated Carbon Materials as Promoters in Energy Harvesting and Storage Technologies”, project No LZP-2018/1-0194, “New biomass origin materials hybrid carbon composites for energy storage” project No LZP-2020/2-0019 and postdoc project “Nitrogen and phosphorus-containing biomass based activated carbons for fuel cells and supercapacitors” project No 1.1.1.2/VIAA/4/20/596.

A new nature of microporous architecture with hierarchical porosity and membrane template via high strain rate collision

2019

Abstract This paper presents the formation of an unusual porous structure at Al/Al interface joined by magnetic pulse welding. The porous structure consists of a hierarchical microporous architecture with pore size of less than 2 µm that represents more than 80% over the whole area, in which 38% of them are sub-micron size pores. It also exhibits ultra-thin wall, sufficiently thin enough to behave as an electron-transparent material with a wall thickness of 50 nm. The formation of this porous structure is attributed to a cavitation process of a molten material in three stages including, (1) nucleation, (2) growth and coalescence and (3) solidification. Further analysis of this cavitation pr…

POLYMERIC POROUS STRUCTURES VIA PHASE SEPARATION

2012

Efficient H2 production by photocatalytic water splitting under UV or solar light over variously modified TiO2-based catalysts

2019

Abstract This paper focused for the first time on the comparison between three different approach to modify the chemico-physical properties of TiO2-based photocatalysts and their effect in the H2 production by photocatalytic water splitting both under UV and solar light irradiation, under the same experimental conditions. The application of pulsed laser irradiation to aqueous TiO2 suspensions (first approach) induced structural transformations both on the bulk and on the surface of TiO2, boosting the H2 production, under UV light irradiation, of almost three times (20.9 mmol/gcat·h) compared to bare TiO2 (7.7 mmol/gcat·h). The second strategy was based on a templating method to obtain TiO2 …

Inverse opal TiO2 as visible-light driven photocatalysts

2017

Semiconductor photocatalysts have attracted a great deal of attention due to their potential application in environmental remediation. Titanium dioxide has been extensively investigated as the most promising photocatalyst. To improve the optical response of TiO2 in the visible region, Inverse Opal TiO2 has been recognized as an efficient photocatalyst due to its unique properties in terms of uniformly ordered and interconnected macroporous architecture.

Effect of Polyhydroxyalkanoate (PHA) Concentration on Polymeric Scaffolds Based on Blends of Poly-L-Lactic Acid (PLLA) and PHA Prepared via Thermally…

2022

Hybrid porous scaffolds composed of both natural and synthetic biopolymers have demonstrated significant improvements in the tissue engineering field. This study investigates for the first time the fabrication route and characterization of poly-L-lactic acid scaffolds blended with polyhydroxyalkanoate up to 30 wt%. The hybrid scaffolds were prepared by a thermally induced phase separation method starting from ternary solutions. The microstructure of the hybrid porous structures was analyzed by scanning electron microscopy and related to the blend composition. The porosity and the wettability of the scaffolds were evaluated through gravimetric and water contact angle measurements, respective…